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Science · Honors Chemistry

Chapter 1: Quantitative Foundations

Error and Propagation

Significant figures are an approximation to something exact.

Lesson
1
Time
About 25 minutes
0 of 10 done
Part 1 of 9Something to Notice
Practice
Using mathematics and computational thinking
Crosscutting concept
Scale, proportion, and quantity
Core idea
PS1.A: Structure and Properties of Matter

Step 1: Something to Notice

Watch first. The explanation comes later.

Watch the idea first — 40 seconds. Then read on, and try it yourself in the next step.

Two measurements each precise to four significant figures are subtracted, and the answer has none.

Where did the precision go?

Step 2: Find Out

Isolate the operation and note which uncertainty — absolute or relative — is preserved.

Step 1 — Predict

Why do the addition and multiplication significant-figure rules differ?

Choose what you think will happen. You cannot see the experiment until you do — guessing first is what makes it worth watching.

Step 3: So Here Is Why

Now the explanation, after you have seen it happen.

Independent

Accuracy is closeness to the truth; precision is closeness of repeats to each other.

Precision How closely repeated measurements agree with one another.

Repetition cannot detect systematic error

Calibrate instead

A mis-calibrated balance gives precise wrong answers indefinitely.

Systematic error A consistent bias that repetition cannot reveal or reduce.

Adding: absolute uncertainties add

Decimal places

12.0 ± 0.1 plus 10.0 ± 0.1 gives 22.0 ± 0.2.

Multiplying: relative uncertainties add

Figure count

0.8% and 1.0% give 1.8% in the product.

Subtracting close values destroys precision

Design around it

The absolute uncertainty survives while the value collapses.

Significant figures approximate something exact

Proper error propagation combines uncertainties by defined rules. Significant figures are a rough substitute that works well enough for routine work and breaks down for careful measurement.

Random and systematic error differ

Random error scatters results around the true value and is reduced by repeating. Systematic error shifts them all one way and is not, which is why more trials cannot fix a miscalibrated instrument.

Step 4: A Common Mistake

Lots of people think

The significant-figure rules for adding and for multiplying are two unrelated conventions to memorize.

Step 5: Why the Mars Climate Orbiter Was Lost

The same idea somewhere new.

In 1999 a spacecraft was lost because one team supplied thrust data in pound-seconds while the receiving software expected newton-seconds. Nothing was imprecise: every number was correct to many figures in its own unit, and the trajectory was wrong by the ratio 4.45 throughout. It is a useful corrective to the impression that quantitative care means carrying more decimal places — the failure was a units error of the kind dimensional analysis exists to catch, and no amount of precision would have detected it.

Units, not digits

Step 6: Think It Through

Practice makes it stick.

Where the Precision Went

Problem 1 of 2

Two four-figure measurements are subtracted and the answer has none. Why?

The Mis-Calibrated Balance

Problem 2 of 2

A balance reads 0.5 g high every time. Will averaging more readings help?

Carrying the Uncertainty

1 of 5

What propagates when quantities are added?

2 of 5

What propagates when quantities are multiplied?

3 of 5

Can repetition reduce systematic error?

4 of 5

How many significant figures does a counted quantity have?

5 of 5

When do the shortcut rules fail?

Step 7: Quick Check

Show what you know.

Question 1 of 1

Are the addition and multiplication significant-figure rules unrelated conventions?

Step 8: Explain It in Writing

Claim, evidence, then reasoning.

The question

Explain the significant-figure rules by deriving them from uncertainty propagation.

Fill in all three boxes. The reasoning box is the one that matters most.

What You Found Out

  • Accuracy and precision are independent, and repetition improves only the second.
  • Absolute uncertainties add for sums; relative uncertainties add for products.
  • Both significant-figure rules are approximations to that propagation.
  • Subtracting close values keeps the uncertainty and destroys the value.