Monomers join by condensation, removing water; hydrolysis adds water and reverses it.
Condensation reaction A reaction joining two monomers with the removal of a water molecule.
Science · Honors Biology
Chapter 1: Biochemistry
Same elements, different arrangement, different job.
Watch first. The explanation comes later.
A cow lives on grass and a human cannot digest it, although both can digest potato — and both polymers are made of the same sugar.
What differs, if the monomer does not?
Isolate the number of monomer units and note what is removed at each linkage.
Step 1 — Predict
Starch and cellulose are both glucose polymers. Why is only one digestible by humans?
Choose what you think will happen. You cannot see the experiment until you do — guessing first is what makes it worth watching.
Now the explanation, after you have seen it happen.
Monomers join by condensation, removing water; hydrolysis adds water and reverses it.
Condensation reaction A reaction joining two monomers with the removal of a water molecule.
Alpha linkages coil and can be digested; beta linkages straighten and cannot.
About 38 kJ per gram against 17, and without associated water.
A cis double bond kinks the chain and prevents tight packing, giving oils.
Saturated A fatty acid chain with no carbon–carbon double bonds.
A water-loving head and water-avoiding tails, so bilayers form on their own.
Amphipathic Having both a water-attracting and a water-avoiding region.
Carbohydrates and lipids are both built from carbon, hydrogen and oxygen. Lipids have far less oxygen relative to carbon, which is why they store roughly twice the energy per gram.
Saturated chains pack tightly and are solid at room temperature; double bonds kink the chain and keep it liquid. The same principle governs membrane fluidity.
Lots of people think
“Starch and cellulose are different molecules because they are made of different sugars.”
The same idea somewhere new.
Partial hydrogenation of vegetable oils was introduced to make cheap solid fats, and it converts some cis double bonds to trans, which straightens the chain and lets it pack like a saturated fat while remaining chemically unsaturated. That shape change is the point: trans fatty acids behave like saturated fats in a membrane and in the bloodstream, and epidemiological evidence eventually linked them to cardiovascular disease strongly enough that many countries banned them. The molecule differs from its harmless isomer only in the geometry around one double bond.
Practice makes it stick.
Grass and Potato
Problem 1 of 2
Both are glucose polymers. Why can a human digest only one?
Solid or Oil
Problem 2 of 2
Why is a saturated fat solid and an unsaturated oil liquid at room temperature?
1 of 5
What is removed when two monomers join?
2 of 5
What distinguishes starch from cellulose?
3 of 5
Why do lipids store more energy per gram?
4 of 5
What does a cis double bond do to a fatty acid chain?
5 of 5
Why do phospholipids form bilayers spontaneously?
Show what you know.
Question 1 of 1
Are starch and cellulose made of different sugars?
Claim, evidence, then reasoning.
The question
Explain why starch and cellulose differ in function, and why lipids store more energy than carbohydrates.
Fill in all three boxes. The reasoning box is the one that matters most.